2D supplies, given their form-factor, excessive surface-to-volume ratio, and chemical performance have immense use in sensor design. Engineering 2D heterostructures can lead to sturdy mixtures of fascinating properties however sensor design methodologies require cautious issues about materials properties and orientation to maximise sensor response. This examine introduces a sensor strategy that mixes the wonderful electrical transport and transduction properties of graphite movie with chemical reactivity derived from the sting websites of semiconducting molybdenum disulfide (MoS2) via a two-step chemical vapour deposition technique. The ensuing vertical heterostructure exhibits potential for high-performance hybrid chemiresistors for gasoline sensing. This structure affords lively sensing edge websites throughout the MoS2 flakes We element the expansion of vertically oriented MoS2 over a nanoscale graphite movie (NGF) cross-section, enhancing the adsorption of analytes equivalent to NO2, NH3, and water vapor. Raman spectroscopy, density practical concept calculations and scanning probe strategies elucidate the affect of chemical doping by distinguishing the position of MoS2 edge websites relative to the basal airplane. Excessive-resolution imaging methods verify the managed development of extremely crystalline hybrid buildings. The MoS2/NGF hybrid construction reveals distinctive chemiresistive responses at each room and elevated temperatures in comparison with naked graphitic layers. Quantitative evaluation reveals that the sensitivity of this hybrid sensor surpasses different 2D materials hybrids, significantly in elements per billion concentrations.